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A theoretical spectroscopy study of the X3Sigma- and the A3Pi states of the C2S radical

Authors :
Nicholas C. Handy
Riccardo Tarroni
Stuart Carter
Dipartimento di Chimica Fisica ed Inorganica
Alma Mater Studiorum Università di Bologna [Bologna] (UNIBO)
University of Reading (UOR)
Chemistry
University of Cambridge [UK] (CAM)
R. Tarroni
S. Carter
N. C. Handy
Source :
Molecular Physics, Molecular Physics, Taylor & Francis, 2007, 105 (09), pp.1129-1137. ⟨10.1080/00268970701218704⟩
Publication Year :
2007
Publisher :
HAL CCSD, 2007.

Abstract

International audience; The spin-rovibronic levels for the X3Sigma-,A3Pi electronic system of C2S are calculated variationally, using ab initio potential energy surfaces and taking into account the non-adiabatic coupling between the two states. The energies of selected levels with Sigma and Pi vibronic symmetry, up to approx 16500 cm-1, are reported and compared with available experimental data.

Details

Language :
English
ISSN :
00268976 and 13623028
Database :
OpenAIRE
Journal :
Molecular Physics, Molecular Physics, Taylor & Francis, 2007, 105 (09), pp.1129-1137. ⟨10.1080/00268970701218704⟩
Accession number :
edsair.doi.dedup.....9faad6a9ccb797af762a452f19742421
Full Text :
https://doi.org/10.1080/00268970701218704⟩