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Nickel(0)-Induced β-H Elimination of Magnesium Alkyls: Formation and Reactivity of Heterometallic Hydrides
- Source :
- INORGANIC CHEMISTRY, INORGANIC CHEMISTRY, 2020, 59 (18), pp.13473-13480. ⟨10.1021/acs.inorgchem.0c01885⟩
- Publication Year :
- 2020
-
Abstract
- We report the synthesis and reactivity of heterometallic Mg-Ni complexes with bridging hydrides. Treatment of magnesium monoalkyl complexes, which are supported by a tridentate β-diketiminato ligand bearing a pendent phosphine group, with nickel(0) reagent Ni(COD)
Details
- ISSN :
- 1520510X
- Volume :
- 59
- Issue :
- 18
- Database :
- OpenAIRE
- Journal :
- Inorganic chemistry
- Accession number :
- edsair.doi.dedup.....9f9f98751d22cb5bbf10819b665ef56a
- Full Text :
- https://doi.org/10.1021/acs.inorgchem.0c01885⟩