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Synthesis and fluorescence properties of Eu-anthracene-9-carboxylic acid towards N-acetyl amino acids and nucleotides in different solvents
- Source :
- Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. 75(1)
- Publication Year :
- 2009
-
Abstract
- Europium (III) complex with anthracene-9-carboxylic acid (9-AA) has been synthesized and characterized by elemental analysis, FT-IR, and TG-DTG techniques. The results indicated that the composition of this complex is Eu (9-AA)(3). The luminescence properties of the complex in different solvents and at different pH values have been investigated. The results show that the complex exhibits more efficient luminescence in THF and ethyl acetate. The interactions of Eu-complex with different N-acetyl amino acids and nucleotides in different solvents have been investigated by fluorescence measurements. Enhancement of the fluorescence intensities has been observed in cyclohexane, acetone, acetonitrile, and tetrahydrofuran whereas the fluorescence intensities of the investigated complex in ethanol, water, and ethyl acetate exhibit relatively low intensity.
- Subjects :
- Luminescence
Spectrophotometry, Infrared
Carboxylic acid
Ethyl acetate
chemistry.chemical_element
Photochemistry
Fluorescence
Analytical Chemistry
chemistry.chemical_compound
Europium
Amino Acids
Acetonitrile
Instrumentation
Spectroscopy
Tetrahydrofuran
chemistry.chemical_classification
Anthracenes
Anthracene
Molecular Structure
Nucleotides
Temperature
Hydrogen-Ion Concentration
Atomic and Molecular Physics, and Optics
Adenosine Diphosphate
Spectrometry, Fluorescence
chemistry
Luminescent Measurements
Solvents
Thermodynamics
Solvent effects
Nuclear chemistry
Subjects
Details
- ISSN :
- 18733557
- Volume :
- 75
- Issue :
- 1
- Database :
- OpenAIRE
- Journal :
- Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
- Accession number :
- edsair.doi.dedup.....9e9d2c5538c7ccd60ff3baab76736172