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Solution Processed Organic Photovoltaic Cells Using D-A-D-A-D Type Small Molecular Donor Materials with Benzodithiophene and Diketopyrrolopyrrole Units
- Source :
- Journal of Nanoscience and Nanotechnology. 16:2787-2791
- Publication Year :
- 2016
- Publisher :
- American Scientific Publishers, 2016.
-
Abstract
- Organic photovoltaic Cells (OPVs) have been considered to be a next-generation energy source to overcome exhaustion of resources. Currently, OPVs are developed based on two types of donor material with polymer and small molecule. Polymeric donor materials have shown better power conversion efficiency (PCE) than small molecular donor materials, since it's easy to control the morphology of photoactive film. However, the difficulty in synthetic reproducibility and purification of polymeric donor were main drawback to overcome. And then, recently small molecule donor materials have been overcome bad morphology of OPVs film by using appropriate alkyl substituents and relatively long conjugation system. In this study, we designed and synthesized D-A-D-A-D type small molecular donor materials containing alternatively linked benzodithiophene (BDT) and diketopyrrolopyrrole (DPP) units. Also, we studied on the effect of photovoltaic performance of prepared small molecular D-A-D-A-D type donor with variation of thiophene links and with/without hexyl substituent. Our small molecular donors showed HOMO energy levels from -5.26 to -5.34 eV and optical bandgaps from 1.70 to 1.87 eV by CV (cyclic voltammetry) and UV/Vis spectroscopy, respectively. Finally, 3.4% of PCE can be obtained using a mixture of BDT(DPP)2-T2 and PCBM as an active layer with a Voc of 0.78 V, a Jsc of 9.72 mA/cm2, and a fill factor of 0.44 under 100 mW/cm2 AM 1.5G simulated light. We will discuss the performance of D-A-D-A-D type small molecular donor based OPVs with variation of both terminal substituents.
- Subjects :
- Materials science
Proton Magnetic Resonance Spectroscopy
Biomedical Engineering
Substituent
Bioengineering
Thiophenes
Microscopy, Atomic Force
010402 general chemistry
Photochemistry
01 natural sciences
chemistry.chemical_compound
Thiophene
Pyrroles
General Materials Science
Alkyl
chemistry.chemical_classification
010405 organic chemistry
Energy conversion efficiency
General Chemistry
Polymer
Ketones
Condensed Matter Physics
Small molecule
0104 chemical sciences
chemistry
Cyclic voltammetry
Energy source
Subjects
Details
- ISSN :
- 15334899 and 15334880
- Volume :
- 16
- Database :
- OpenAIRE
- Journal :
- Journal of Nanoscience and Nanotechnology
- Accession number :
- edsair.doi.dedup.....9e5bea95bcbb6725d18ca94381e1e8dc