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SuFEx‐Enabled Elastic Polysulfates for Efficient Removal of Radioactive Iodomethane and Polar Aprotic Organics through Weak Intermolecular Forces
- Source :
- Angewandte Chemie International Edition. 61
- Publication Year :
- 2022
- Publisher :
- Wiley, 2022.
-
Abstract
- Capturing radioactive iodomethane and its vapors is a major challenge due to its low adsorption capacity. Herein, we have developed for the first time a pyridine-entrapped elastic crosslinked polysulfate gel (pyridine/TPC-cPS) as an efficient absorbent for iodomethane capture. Each pyridine-encased TPC-cPS network cell acts as a mini-reactor for salt formation between pyridine and iodomethane. The yield reaches up to 96.65 % and traps saturated iodomethane vapor of 1.573 g g
- Subjects :
- General Medicine
General Chemistry
Catalysis
Subjects
Details
- ISSN :
- 15213773 and 14337851
- Volume :
- 61
- Database :
- OpenAIRE
- Journal :
- Angewandte Chemie International Edition
- Accession number :
- edsair.doi.dedup.....9d2f984fecdadcc64a5fceb7d6763116
- Full Text :
- https://doi.org/10.1002/anie.202208577