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Conversion of birch bark to biofuels

Authors :
Vincent Placet
Natalia Crespo Mendes
Karel Van Acker
Joseph S. M. Samec
Kranti Navare
Ivan Kumaniaev
Univeristy of Stockholm (Univeristy of Stockholm)
Franche-Comté Électronique Mécanique, Thermique et Optique - Sciences et Technologies (UMR 6174) (FEMTO-ST)
Université de Technologie de Belfort-Montbeliard (UTBM)-Ecole Nationale Supérieure de Mécanique et des Microtechniques (ENSMM)-Université de Franche-Comté (UFC)
Université Bourgogne Franche-Comté [COMUE] (UBFC)-Université Bourgogne Franche-Comté [COMUE] (UBFC)-Centre National de la Recherche Scientifique (CNRS)
Source :
Green Chemistry, Green Chemistry, 2020, 22, pp.2255-2263. ⟨10.1039/D0GC00405G⟩
Publication Year :
2020
Publisher :
ROYAL SOC CHEMISTRY, 2020.

Abstract

International audience; Substitution of fossil energy sources for bio-based ones will require development of efficient processes that can convert inedible and preferably low-value fractions that currently are not used into high-value products. It is desirable that such processes are developed so that both current logistics and infrastructure can be used. Bark, which is the outer layer of woody biomass, is currently burnt in a low-value process or left in the forests to decay and is therefore considered waste. In this work, birch (Betula pendula) bark was converted to hydrocarbons suitable for use in both road and aviation fuels in two efficient steps. Development of an efficient, recyclable, salt- and metal-free solvent-based system to solubilize birch bark under benign reaction conditions was a key outcome. The obtained gum was composed of organosolv lignin and suberin oligomers and was fully characterized. This gum had unique properties and could be directly processed in a conventional hydroprocessing unit set-up to afford hydrocarbons in the road and aviation fuel ranges. Life cycle assessment was applied to evaluate different scenarios for implementing this technology. When using bark generated as a forestry by-product and current infrastructure in a pulp mill, the process had a favorable low carbon dioxide footprint for biofuel generation.

Details

Language :
English
Database :
OpenAIRE
Journal :
Green Chemistry, Green Chemistry, 2020, 22, pp.2255-2263. ⟨10.1039/D0GC00405G⟩
Accession number :
edsair.doi.dedup.....9d18c5982d4270e32d9ae223d783f294
Full Text :
https://doi.org/10.1039/D0GC00405G⟩