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Stabilisation of camelina oil methyl esters through selective hydrogenation

Authors :
Sergio Mapelli
Paolo Bondioli
Incoronata Galasso
Federica Zaccheria
Nicoletta Ravasio
Paola Pecchia
Source :
Industrial crops and products, 51 (2013): 306–309. doi:10.1016/j.indcrop.2013.09.021, info:cnr-pdr/source/autori:Pecchia, Paola; Galasso, Incoronata; Mapelli, Sergio; Bondioli, Paolo; Zaccheria, Federica; Ravasio, Nicoletta/titolo:Stabilisation of camelina oil methyl esters through selective hydrogenation/doi:10.1016%2Fj.indcrop.2013.09.021/rivista:Industrial crops and products (Print)/anno:2013/pagina_da:306/pagina_a:309/intervallo_pagine:306–309/volume:51
Publication Year :
2013
Publisher :
Elsevier BV, 2013.

Abstract

Camelina sativa (L.) Crantz in the last few years is garnering a lot of attention as a biofuel and as raw material for the chemical industry due to its high oil productivity. However the high percentage of polyunsaturated fatty acids of camelina oil (over 50%), which is rich in linolenic acid (37–40%) limits its commercial value and large-scale production. To improve the oil quality and its oxidative stability the methyl esters have been selectively hydrogenated using a non-toxic and non-pyrophoric heterogeneous copper catalyst (Cu/SiO 2 or Cu/Al 2 O 3 ). Our results showed that both catalysts are able to reduce the linolenic acid content below 1% while selectively increasing the monounsaturated one.

Details

ISSN :
09266690
Volume :
51
Database :
OpenAIRE
Journal :
Industrial Crops and Products
Accession number :
edsair.doi.dedup.....9d093f5260cc9e4e8ad0b48aa88921b4
Full Text :
https://doi.org/10.1016/j.indcrop.2013.09.021