Rapid Injection NMR Reveals η3 ‘π-Allyl’ CuIII Intermediates in Addition Reactions of Organocuprate Reagents

Authors :: Steven H. Bertz
Michael D. Murphy
Richard A. Hardin
Andy A. Thomas
Craig A. Ogle
Joshua D. Richter
Source :: Journal of the American Chemical Society. 134:9557-9560
Publication Year :: 2012
Publisher :: American Chemical Society (ACS), 2012.
Abstract: By using rapid injection NMR, it has now been possible to prepare and characterize the η(3) 'π-allyl' copper(III) intermediate that has been proposed for addition reactions of organocopper(I) reagents and α,β-unsaturated carbonyl compounds.

Subjects :: Addition reaction
Colloid and Surface Chemistry
chemistry
Reagent
Organic chemistry
chemistry.chemical_element
General Chemistry
Biochemistry
Copper
Catalysis

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