Back to Search
Start Over
Double Helices of a Pyridine-Appended Zinc Chlorophyll Derivative
- Source :
- Journal of the American Chemical Society. 135:5262-5265
- Publication Year :
- 2013
- Publisher :
- American Chemical Society (ACS), 2013.
-
Abstract
- Self-assembled structures formed from a pyridine-appended zinc chlorophyll derivative are reported. While the zinc complex forms cyclic oligomers in chloroform solution, as indicated by (1)H NMR studies (including diffusion-ordered spectroscopy), vapor pressure osmometry, and cold-spray ionization mass spectrometry, it forms double-stranded helical coordination polymers in the solid state, as revealed by single-crystal X-ray analysis.
- Subjects :
- Chlorophyll
Models, Molecular
Chloroform
Molecular Structure
Pyridines
Vapor pressure osmometry
Inorganic chemistry
chemistry.chemical_element
General Chemistry
Zinc
Biochemistry
Catalysis
chemistry.chemical_compound
Crystallography
Colloid and Surface Chemistry
chemistry
Coordination Complexes
Pyridine
Proton NMR
Spectroscopy
Derivative (chemistry)
Subjects
Details
- ISSN :
- 15205126 and 00027863
- Volume :
- 135
- Database :
- OpenAIRE
- Journal :
- Journal of the American Chemical Society
- Accession number :
- edsair.doi.dedup.....9b9961968c215ec88d09a6a7ec201584