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Unveiling the Stable Nature of the Solid Electrolyte Interphase between Lithium Metal and LiPON via Cryogenic Electron Microscopy
- Source :
- Joule, vol 4, iss 11
- Publication Year :
- 2020
- Publisher :
- eScholarship, University of California, 2020.
-
Abstract
- The solid electrolyte interphase (SEI) is regarded as the most complex but the least understood constituent in secondary batteries using liquid and solid electrolytes. The nanostructures of SEIs were recently reported to be equally important to the chemistry of SEIs for stabilizing Li metal in liquid electrolyte. However, the dearth of such knowledge in all-solid-state battery (ASSB) has hindered a complete understanding of how certain solid-state electrolytes, such as LiPON, manifest exemplary stability against Li metal. Characterizing such solid-solid interfaces is difficult due to the buried, highly reactive, and beam-sensitive nature of the constituents within. By employing cryogenic electron microscopy (cryo-EM), the interphase between Li metal and LiPON is successfully preserved and probed, revealing a multilayer mosaic SEI structure with concentration gradients of nitrogen and phosphorous, materializing as crystallites within an amorphous matrix. This unique SEI nanostructure is less than 80 nm and is shown stable and free of any organic lithium containing species or lithium fluoride components, in contrast to SEIs often found in state-of-the-art organic liquid electrolytes. Our findings reveal insights on the nanostructures and chemistry of such SEIs as a key component in lithium metal batteries to stabilize Li metal anode.
- Subjects :
- Battery (electricity)
Condensed Matter - Materials Science
Materials science
Nanostructure
Lithium fluoride
Materials Science (cond-mat.mtrl-sci)
FOS: Physical sciences
02 engineering and technology
Electrolyte
Applied Physics (physics.app-ph)
Physics - Applied Physics
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
0104 chemical sciences
Anode
chemistry.chemical_compound
General Energy
Chemical engineering
chemistry
Fast ion conductor
Interphase
Crystallite
0210 nano-technology
Subjects
Details
- Database :
- OpenAIRE
- Journal :
- Joule, vol 4, iss 11
- Accession number :
- edsair.doi.dedup.....9a3ffc5345852180c0f87990a055e269