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Superior Impact Toughness and Excellent Storage Modulus of Poly(lactic acid) Foams Reinforced by Shish-Kebab Nanoporous Structure
- Source :
- ACS applied materialsinterfaces. 9(25)
- Publication Year :
- 2017
-
Abstract
- Poly(lactic acid) (PLA) foams, with the combination of shish-kebab and spherulite nanoporous structure in skin and core layer respectively, was prepared using a novel technique comprising loop oscillating push–pull molding (LOPPM) and supercritical carbon dioxide low-temperature foaming process (SC−CO2LTFP). The foams present superior impact toughness which is 6-fold higher than that of neat PLA, and no significant decrease was observed for the storage modulus. Moreover, SC−CO2LTFP at soaking temperature ranging from 110 to 150 °C were performed to determine the evolution of pore morphology. The ultratough and supermoduli are unprecedented for PLA, and are in great need for broader applications.
- Subjects :
- Materials science
Supercritical carbon dioxide
Nanoporous
Core (manufacturing)
02 engineering and technology
Dynamic mechanical analysis
Molding (process)
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
0104 chemical sciences
Lactic acid
chemistry.chemical_compound
chemistry
Spherulite
Shish kebab
General Materials Science
Composite material
0210 nano-technology
Subjects
Details
- ISSN :
- 19448252
- Volume :
- 9
- Issue :
- 25
- Database :
- OpenAIRE
- Journal :
- ACS applied materialsinterfaces
- Accession number :
- edsair.doi.dedup.....99cb7f28f1c3f52b5ca490ca2b98b37e