Back to Search
Start Over
Quadrupole relaxation enhancement and polarisation transfer in DMSO solution of [Bi(NO 3 ) 3 (H 2 O) 3 ]*18-crown-6 in solid state
- Source :
- Molecular Physics
- Publication Year :
- 2018
- Publisher :
- Zenodo, 2018.
-
Abstract
- 1H spin-lattice relaxation studies have been performed for pure [Bi(NO3)3(H2O)3]*18-crown-6 in powder and its solution in dimethyl sulfoxide (DMSO). The experiments have been carried out in the frequency range of 10 kHz–30MHz and the temperature range of 240–277 K; at 277 K the solution is already frozen. The 1Hrelaxation of pure [Bi(NO3)3(H2O)3]*18-crown-6 has been interpreted in terms of three dynamical processes. Quadrupole Relaxation Enhancement effects have been observed in the frozen DMSO solution of [Bi(NO3)3(H2O)3]*18-crown-6. The specific mechanisms of the 1H spin- lattice relaxation enhancement have been discussed distinguishing between effects caused by time independent (residual) and fluctuating 1H-209Bi dipole-dipole interactions.
- Subjects :
- Materials science
010304 chemical physics
Dimethyl sulfoxide
18-Crown-6
Biophysics
Solid-state
010402 general chemistry
Condensed Matter Physics
01 natural sciences
NMR
relaxation
quadrupole peaks
polarization transfer
0104 chemical sciences
chemistry.chemical_compound
chemistry
0103 physical sciences
Quadrupole
Relaxation (physics)
Physical chemistry
Physical and Theoretical Chemistry
Molecular Biology
Subjects
Details
- Database :
- OpenAIRE
- Journal :
- Molecular Physics
- Accession number :
- edsair.doi.dedup.....9810f8e33ffdcdf917a8d210f7ef5507