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Shifting and broadening in the fundamental band of CO highly diluted in He and Ar: A comparison with theory
- Source :
- Journal of Chemical Physics, Journal of Chemical Physics, American Institute of Physics, 2001, 115 (5), pp.2198-220. ⟨10.1063/1.1383049⟩, Journal of Chemical Physics, 2001, 115 (5), pp.2198-220. ⟨10.1063/1.1383049⟩
- Publication Year :
- 2001
- Publisher :
- HAL CCSD, 2001.
-
Abstract
- We present measurements of the shifts and widths of the rovibrational lines of the fundamental band of CO highly diluted in He and Ar at 296 K. The shifts are decomposed into parts odd and even in the line number, m. These are then compared with close coupled calculations carried out with the best known interaction potentials. There is general agreement between the calculated and measured values of the broadening and shifting. Furthermore, the results illustrate that the decomposition of the shifts into parts, odd and even in m, is a powerful tool for separating out the relative contributions of the isotropic and anisotropic part of the interaction to the shifts and which part needs to be corrected if there is a discrepancy. Thus, shift measurements can be added to the list of experiments that may be used to determine reliable interaction potentials. The results also show, given a potential, that close coupled calculations are accurate and could be used to confirm or establish empirical models of the temperature dependence of the broadening or shifting, etc. Such modeling is important at atmospheric physics.
- Subjects :
- [PHYS]Physics [physics]
[SDU.OCEAN]Sciences of the Universe [physics]/Ocean, Atmosphere
Atmospheric physics
010304 chemical physics
Chemistry
Isotropy
Empirical modelling
General Physics and Astronomy
Rotational–vibrational spectroscopy
01 natural sciences
[CHIM.THEO]Chemical Sciences/Theoretical and/or physical chemistry
[PHYS.QPHY]Physics [physics]/Quantum Physics [quant-ph]
0103 physical sciences
[CHIM]Chemical Sciences
Physical and Theoretical Chemistry
Atomic physics
010306 general physics
Anisotropy
ComputingMilieux_MISCELLANEOUS
Doppler broadening
Subjects
Details
- Language :
- English
- ISSN :
- 00219606 and 10897690
- Database :
- OpenAIRE
- Journal :
- Journal of Chemical Physics, Journal of Chemical Physics, American Institute of Physics, 2001, 115 (5), pp.2198-220. ⟨10.1063/1.1383049⟩, Journal of Chemical Physics, 2001, 115 (5), pp.2198-220. ⟨10.1063/1.1383049⟩
- Accession number :
- edsair.doi.dedup.....97d025d11d9faf9c2f3f18150a87d8a4