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Bis[4-(dimethylamino)pyridinium] tetrachloridozincate
- Source :
- Acta Crystallographica Section E: Structure Reports
- Publication Year :
- 2011
- Publisher :
- International Union of Crystallography, 2011.
-
Abstract
- In the title compound, (C(7)H(11)N(2))(2)[ZnCl(4)], [ZnCl(4)](2-) anions and 4-(dimethyl-amino)-pyridinium cations are held together by various inter-molecular inter-actions including Coulombic attraction, hydrogen bonding and π-π stacking inter-actions. Three Cl atoms of the [ZnCl(4)](2-) tetra-hedron act as acceptors in N-H⋯Cl hydrogen bonds. The hydrogen bonds, both of which are bifurcated, lead to the formation of a three-dimensional network. Within the network, inter-molecular π-π stacking inter-actions with a centroid-centroid distance of 3.5911 (7) Å arrange the 4-(dimethyl-amino)-pyridinium cations into anti-parallel dimers.
- Subjects :
- Metal-Organic Papers
biology
010405 organic chemistry
Chemistry
Hydrogen bond
Stacking
General Chemistry
010402 general chemistry
Condensed Matter Physics
biology.organism_classification
Bioinformatics
01 natural sciences
0104 chemical sciences
3. Good health
chemistry.chemical_compound
Crystallography
Tetra
General Materials Science
Pyridinium
Subjects
Details
- Language :
- English
- ISSN :
- 16005368
- Volume :
- 67
- Issue :
- Pt 3
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E: Structure Reports Online
- Accession number :
- edsair.doi.dedup.....95fa70393b5fa7c675378f5d9644975b