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Bis[4-(dimethyl­amino)­pyridinium] tetra­chloridozincate

Authors :
R. Kefi
Ben Nasr C
Matthias Zeller
Frédéric Lefebvre
Source :
Acta Crystallographica Section E: Structure Reports
Publication Year :
2011
Publisher :
International Union of Crystallography, 2011.

Abstract

In the title compound, (C(7)H(11)N(2))(2)[ZnCl(4)], [ZnCl(4)](2-) anions and 4-(dimethyl-amino)-pyridinium cations are held together by various inter-molecular inter-actions including Coulombic attraction, hydrogen bonding and π-π stacking inter-actions. Three Cl atoms of the [ZnCl(4)](2-) tetra-hedron act as acceptors in N-H⋯Cl hydrogen bonds. The hydrogen bonds, both of which are bifurcated, lead to the formation of a three-dimensional network. Within the network, inter-molecular π-π stacking inter-actions with a centroid-centroid distance of 3.5911 (7) Å arrange the 4-(dimethyl-amino)-pyridinium cations into anti-parallel dimers.

Details

Language :
English
ISSN :
16005368
Volume :
67
Issue :
Pt 3
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E: Structure Reports Online
Accession number :
edsair.doi.dedup.....95fa70393b5fa7c675378f5d9644975b