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Modular Synthesis of Arylacetic Acid Esters, Thioesters, and Amides from Aryl Ethers via Rh(II)-Catalyzed Diazo Arylation
- Source :
- Journal of Organic Chemistry, Journal of Organic Chemistry, American Chemical Society, 2016, 81 (17), pp.7760--7770. ⟨10.1021/acs.joc.6b01426⟩, Journal of Organic Chemistry, 2016, 81 (17), pp.7760--7770. ⟨10.1021/acs.joc.6b01426⟩
- Publication Year :
- 2016
- Publisher :
- American Chemical Society (ACS), 2016.
-
Abstract
- International audience; One-pot formation of arylacetic acid esters, thioesters, and amides via Rh(II)-catalyzed arylation of a Meldrum's acid-derived diazo reagent with electron-rich arenes is described. The methodology was used to efficiently synthesize an anticancer compound. © 2016 American Chemical Society.
- Subjects :
- Aromatic compounds
chemistry.chemical_element
010402 general chemistry
01 natural sciences
Chemical reaction
Catalysis
Arylations
Electron-rich arenes
Rhodium
Diazo reagents
chemistry.chemical_compound
Meldrum's acids
Chemical reactions
[CHIM]Chemical Sciences
Organic chemistry
Aryl ether
Modular synthesis
010405 organic chemistry
Aryl
Organic Chemistry
Esters
Amides
0104 chemical sciences
Anticancer compounds
chemistry
Reagent
Diazo
Arylacetic acids
Subjects
Details
- ISSN :
- 15206904 and 00223263
- Volume :
- 81
- Database :
- OpenAIRE
- Journal :
- The Journal of Organic Chemistry
- Accession number :
- edsair.doi.dedup.....94d9bc2b59f63ca7028bac3a2acacb9e