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Synthesis and Characterization of a Novel Cobalt Carbonyl N-Heterocyclic Carbene Salt. Crystal Structure of [Co(CO)3(IMes)2]+[Co(CO)4]
- Source :
- Inorganic Chemistry. 46:1963-1965
- Publication Year :
- 2007
- Publisher :
- American Chemical Society (ACS), 2007.
-
Abstract
- The disproportionation of dicobalt octacarbonyl induced by the free carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes) and the X-ray characterization of the cyclohexane solvate of the resulting cobalt carbonyl N-heterocyclic carbene salt, [Co(CO)3(IMes)2]+[Co(CO)4] -·1/4C6H12, is reported. The crystal structure represents the first example of a [Co(CO)3(L)2][Co(CO)4] disproportionate salt reported to date.
Details
- ISSN :
- 1520510X and 00201669
- Volume :
- 46
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry
- Accession number :
- edsair.doi.dedup.....94cf6677a8be47ec40bdcf77b44ef226