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A potential method for comparing instrumental analysis of volatile organic compounds using standards calibrated for the gas phase
- Source :
- International Journal of Mass Spectrometry. 419:1-10
- Publication Year :
- 2017
- Publisher :
- Elsevier BV, 2017.
-
Abstract
- In this paper we report a method for the comparative analysis of volatile organic compounds (VOCs) at physiologically representative concentrations by different analytical methods Standard aqueous solutions of acetone, ethanol, methanol, 1-propanol, 2-propanol and acetaldehyde were prepared by adding a specific mass of compound to a known volume of water, calculated using published Henry’s law constants for individual compounds. Headspace concentrations are thus known from established partitioning from dilute aqueous phase in accordance with Henry’s law. Selected Ion Flow Tube Mass Spectrometry (SIFT-MS), Proton Transfer Reaction Mass Spectrometry (PTR-MS), and Gas Chromatography–Mass Spectrometry (GC–MS) coupled to thermal desorption have been used to study and evaluate the performance of the instruments in the analysis of these VOCs. These analytical techniques have been widely used in the identification and quantification of trace concentrations of VOCs in biological samples. Quantitative determination of VOC concentration was achieved and the performance of the instruments compared with one another. Calibration curves are given within the range 101–103 ppbv.
- Subjects :
- Chromatography
Calibration curve
Chemistry
010401 analytical chemistry
Analytical chemistry
Aqueous two-phase system
Thermal desorption
010501 environmental sciences
Condensed Matter Physics
Mass spectrometry
01 natural sciences
0104 chemical sciences
3. Good health
Volume (thermodynamics)
Selected-ion flow-tube mass spectrometry
Physical and Theoretical Chemistry
Gas chromatography–mass spectrometry
Instrumentation
Spectroscopy
Proton-transfer-reaction mass spectrometry
0105 earth and related environmental sciences
Subjects
Details
- ISSN :
- 13873806
- Volume :
- 419
- Database :
- OpenAIRE
- Journal :
- International Journal of Mass Spectrometry
- Accession number :
- edsair.doi.dedup.....9307eafe408ed5aa91925a60ae1de415