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Hindered rotation in an 'exploded' biphenyl

Authors :
K. Peter C. Vollhardt
Sangdon Han
Ognjen Š. Miljanić
Gaston R. Schaller
Daniel Holmes
Source :
Chemical communications (Cambridge, England). (20)
Publication Year :
2005

Abstract

The first cases of hindered rotation around the triple bond in simple diphenylacetylenes were observed, including that in chiral 2,2′-bis(trimethylsilyl)-6,6′-bis(dimethylthexylsilyl)diphenylacetylene.

Details

ISSN :
13597345
Issue :
20
Database :
OpenAIRE
Journal :
Chemical communications (Cambridge, England)
Accession number :
edsair.doi.dedup.....90dad1568994bda38415d19c18378884