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(Salen)Titanium‐Catalyzed Asymmetric Hydrogen Atom Transfer for Epoxides Reduction

(Salen)Titanium‐Catalyzed Asymmetric Hydrogen Atom Transfer for Epoxides Reduction

Authors :
Zhongyun Xu
Jian Shen
Longfei Li
Wanjiao Chen
Shengxiao Li
Jie Jiang
Yong‐Qiang Zhang
Source :
Angewandte Chemie International Edition. 61
Publication Year :
2022
Publisher :
Wiley, 2022.

Abstract

Asymmetric hydrogen atom transfer (HAT) represents arguably one of the most straightforward access to the significant chiral tertiary carbon centers, however, remains a long-standing challenge. Herein, the first example of catalytic coordination-induced asymmetric HAT reaction has been developed relying on a sequential (salen)Ti

Details

ISSN :
15213773 and 14337851
Volume :
61
Database :
OpenAIRE
Journal :
Angewandte Chemie International Edition
Accession number :
edsair.doi.dedup.....9083e231a33c3d4be095bfd25085283c
Full Text :
https://doi.org/10.1002/anie.202214111