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Technetium and rhenium heterocomplexes containing the diphenylphosphinoferrocenyl fragment
- Source :
- Journal of organometallic chemistry, 637 (2001): 772–776. doi:10.1016/S0022-328X(01)00917-2, info:cnr-pdr/source/autori:Tisato F. ; Refosco F.; Porchia M.; Bandoli G.; Pilloni G.; Uccelli L.; Boschi A.; Duatti A./titolo:Technetium and rhenium heterocomplexes containing the diphenylphosphinoferrocenyl fragment/doi:10.1016%2FS0022-328X(01)00917-2/rivista:Journal of organometallic chemistry (Print)/anno:2001/pagina_da:772/pagina_a:776/intervallo_pagine:772–776/volume:637
- Publication Year :
- 2001
- Publisher :
- Elsevier BV, 2001.
-
Abstract
- Reactions of dppf with labile technetium and rhenium precursors such as [M(N)Cl 4 ] − and [M(NPh)Cl 3 (PPh 3 ) 2 ] yield the monomeric mono-substituted [M(N)Cl 2 (dppf)] and [M(NPh)Cl 3 (dppf)] complexes, where the diphosphinoferrocenyl fragment coordinates on the equatorial plane of a distorted square pyramid or of a distorted octahedron, respectively.
- Subjects :
- Stereochemistry
Mixed ligand complexes
Diphenylphosphinoferrocene
Organic Chemistry
Technetium
chemistry.chemical_element
Crystal structures
Nitrido complexes
Rhenium
Crystal structure
Biochemistry
Inorganic Chemistry
Crystallography
chemistry.chemical_compound
Monomer
chemistry
Octahedron
Square pyramid
Yield (chemistry)
Materials Chemistry
Physical and Theoretical Chemistry
Subjects
Details
- ISSN :
- 0022328X
- Database :
- OpenAIRE
- Journal :
- Journal of Organometallic Chemistry
- Accession number :
- edsair.doi.dedup.....8e76e54a9b8f9daeb8b654ea08ba2edd
- Full Text :
- https://doi.org/10.1016/s0022-328x(01)00917-2