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Click inspired synthesis of triazole-linked vanillin glycoconjugates
- Source :
- Glycoconjugate journal. 34(1)
- Publication Year :
- 2016
-
Abstract
- The 1,3-dipolar cycloaddition of deoxy-azido sugars 1 with alkyne derivatives of p-vanillin, 3-methoxy-4-(prop-2-ynyloxy)benzaldehyde (2) and 2-methoxy-1-(prop-2-ynyloxy)-4-((prop-2-ynyloxy)methyl)benzene) (4) to afford regioselective triazole-linked vanillinglycoconjugates 5 and 6 was investigated in the presence of CuI/DIPEA in dichloromethane. All the developed glycoconjugates were characterized on the basis of IR, NMR, and MS. Graphical abstract Triazolyl vanillin glycoconjugates via click chemistry.
- Subjects :
- chemistry.chemical_classification
010405 organic chemistry
Glycoconjugate
Vanillin
Triazole
Alkyne
Regioselectivity
Cell Biology
Triazoles
010402 general chemistry
01 natural sciences
Biochemistry
Cycloaddition
0104 chemical sciences
Benzaldehyde
chemistry.chemical_compound
chemistry
Benzaldehydes
Click chemistry
Organic chemistry
Click Chemistry
Glycosides
Molecular Biology
Glycoconjugates
Subjects
Details
- ISSN :
- 15734986
- Volume :
- 34
- Issue :
- 1
- Database :
- OpenAIRE
- Journal :
- Glycoconjugate journal
- Accession number :
- edsair.doi.dedup.....8e2b7c0325a61255569a9eee8af370df