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A convenient synthesis of anthranilic acids by Pd-catalyzed direct intermolecular ortho-C-H amidation of benzoic acids
- Source :
- Chemical communications (Cambridge, England). 48(95)
- Publication Year :
- 2012
-
Abstract
- An efficient method for synthesis of anthranilic acids by Pd-catalyzed ortho-C–H amidation of benzoic acids is disclosed. The amidation is proposed to proceed by carboxylate-assisted ortho-C–H palladation to form an arylpalladium(II) complex, followed by nitrene insertion to the Pd–C bond.
- Subjects :
- inorganic chemicals
integumentary system
Chemistry
organic chemicals
Nitrene
Carbon chemistry
Intermolecular force
Metals and Alloys
General Chemistry
Benzoates
Carbon
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Coordination Complexes
Materials Chemistry
Ceramics and Composites
Organic chemistry
ortho-Aminobenzoates
Palladium
Hydrogen
Subjects
Details
- ISSN :
- 1364548X
- Volume :
- 48
- Issue :
- 95
- Database :
- OpenAIRE
- Journal :
- Chemical communications (Cambridge, England)
- Accession number :
- edsair.doi.dedup.....8dae791dfd0701d60aace9d2060d209d