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On Classical Ideal Gases

Authors :
Laurent Chusseau
Fabrice Philippe
Jacques Arnaud
Institut d’Electronique et des Systèmes (IES)
Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)
Radiations et composants (RADIAC)
Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)
Systèmes complexes, automates et pavages (ESCAPE)
Laboratoire d'Informatique de Robotique et de Microélectronique de Montpellier (LIRMM)
Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)
Arithmétique informatique (ARITH)
Source :
Entropy, Entropy, MDPI, 2013, 15 (3), pp.960-971. ⟨10.3390/e15030960⟩, Entropy, Vol 15, Iss 3, Pp 960-971 (2013), Volume 15, Issue 3, Pages 960-971
Publication Year :
2013
Publisher :
HAL CCSD, 2013.

Abstract

The ideal gas laws are derived from the democritian concept of corpuscles moving in vacuum plus a principle of simplicity, namely that these laws are independent of the laws of motion aside from the law of energy conservation. A single corpuscle in contact with a heat bath and submitted to a $z$ and $t$-invariant force $-w$ is considered, in which case corpuscle distinguishability is irrelevant. The non-relativistic approximation is made only in examples. Some of the end results are known but the method appears to be novel. The mathematics being elementary the present paper should facilitate the understanding of the ideal-gas law and more generally of classical thermodynamics. It supplements importantly a previously published paper: The stability of ideal gases is proven from the expressions obtained for the force exerted by the corpuscle on the two end pistons of a cylinder, and the internal energy. We evaluate the entropy increase that occurs when the wall separating two cylinders is removed and show that the entropy remains the same when the separation is restored. The entropy increment may be defined at the ratio of heat entering into the system and temperature when the number of corpuscles (0 or 1) is fixed. In general the entropy is defined as the average value of $\ln(p)$ where $p$ denotes the probability of a given state. Generalization to $z$-dependent weights, or equivalently to arbitrary static potentials, is made.<br />Comment: Generalization of previous versions to questions of stability

Details

Language :
English
ISSN :
10994300
Database :
OpenAIRE
Journal :
Entropy, Entropy, MDPI, 2013, 15 (3), pp.960-971. ⟨10.3390/e15030960⟩, Entropy, Vol 15, Iss 3, Pp 960-971 (2013), Volume 15, Issue 3, Pages 960-971
Accession number :
edsair.doi.dedup.....8a756b2c604d59f4bcafb30875cb5dda
Full Text :
https://doi.org/10.3390/e15030960⟩