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Cyclization and annulation reactions of nitrogen-substituted cyclopropanes and cyclobutanes
- Source :
- CHEMICAL COMMUNICATIONS
- Publisher :
- Royal Society of Chemistry
-
Abstract
- Cyclization and annulation reactions initiated by ring-opening of small rings, especially cyclopropanes and cyclobutanes are now well-established in synthetic chemistry. Nevertheless, the potential of aminocyclopropanes and cyclobutanes, an important subclass for the synthesis of nitrogen-rich building blocks, has remained unexploited for a long time, despite important pioneering results. In the last decade, the situation has changed dramatically and new catalytic methods have emerged both for cyclization and annulation reactions. The purpose of this feature article is to present recent progress in this area, including our own work using donor-acceptor cyclopropanes and cyclobutanes.
- Subjects :
- Annulation
Cyclobutanes
cyclization
Cycloaddition Reaction
cyclopropanes
010405 organic chemistry
Chemistry
Nitrogen
Metals and Alloys
Stereoisomerism
General Chemistry
010402 general chemistry
annulation
01 natural sciences
Chemical synthesis
Catalysis
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
cyclobutanes
Materials Chemistry
Ceramics and Composites
Organic chemistry
Palladium
Subjects
Details
- Database :
- OpenAIRE
- Journal :
- CHEMICAL COMMUNICATIONS
- Accession number :
- edsair.doi.dedup.....8997543b247ec918820d5a1f309e6569