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Free-Radical Dispersion Polymerization of Methyl Methacrylate in Supercritical Carbon Dioxide: A Parametric Analysis with Reaction Calorimetry
- Source :
- Macromolecular Reaction Engineering. 1:78-85
- Publication Year :
- 2007
- Publisher :
- Wiley, 2007.
-
Abstract
- In this study, the application of reaction calorimetry, an efficient tool to obtain kinetic and safety data, is presented on the free radical dispersion polymn. of MMA in scCO2. The effect of three major parameters with respect to the reaction evolution are studied, namely of stirrer type and stirring speed, the monomer and CO2 concn. and the stabilizer concn. The effective formation of the dispersion as well as the balance between the polymer formed in the continuous phase or inside the particles are key features of this anal.
- Subjects :
- Dispersion polymerization
polymethyl methacrylate prepn carbon dioxide dispersion polymn
Supercritical carbon dioxide
Polymers and Plastics
Polymerization (dispersion
General Chemical Engineering
Polymer morphology (prepn. and properties of
Radical polymerization
General Chemistry
Supercritical fluid
methacrylate by dispersion polymn. in supercrit. carbon
chemistry.chemical_compound
polyMe methacrylate by dispersion polymn. in supercrit
Reaction calorimeter
Chemical engineering
Polymerization
chemistry
Polymer chemistry
carbon dioxide)
Methyl methacrylate
Dispersion (chemistry)
dioxide)
prepn. and properties of polyMe
Subjects
Details
- ISSN :
- 18628338 and 1862832X
- Volume :
- 1
- Database :
- OpenAIRE
- Journal :
- Macromolecular Reaction Engineering
- Accession number :
- edsair.doi.dedup.....8923ab50b16e12d68024f0a4f6629a28