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Pentavalent Uranium Incorporated in the Structure of Proterozoic Hematite

Authors :
Eugene S. Ilton
Richard N. Collins
Cristiana L. Ciobanu
Nigel J. Cook
Max Verdugo-Ihl
Ashley D. Slattery
David J. Paterson
Sebastian T. Mergelsberg
Eric J. Bylaska
Kathy Ehrig
Source :
Environmental sciencetechnology. 56(16)
Publication Year :
2022

Abstract

Characterizing the chemical state and physical disposition of uranium that has persisted over geologic time scales is key for modeling the long-term geologic sequestration of nuclear waste, accurate uranium-lead dating, and the use of uranium isotopes as paleo redox proxies. X-ray absorption spectroscopy coupled with molecular dynamics modeling demonstrated that pentavalent uranium is incorporated in the structure of 1.6 billion year old hematite (α-Fe

Details

ISSN :
15205851
Volume :
56
Issue :
16
Database :
OpenAIRE
Journal :
Environmental sciencetechnology
Accession number :
edsair.doi.dedup.....85e9a02618c2369dd9a49e7283d9e564