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Dichloro(O-ethyl 3-methylpyridine-2-carboximidic acid-κ2N,N′)copper(II)

Authors :
Dong Ping Cheng
Min Xu
Ri Cheng Xuan
Source :
Acta Crystallographica Section C Crystal Structure Communications. 62:m587-m589
Publication Year :
2006
Publisher :
International Union of Crystallography (IUCr), 2006.

Abstract

In the title compound, [CuCl2(C9H12N2O)], the Cu(II) atom is coordinated by two Cl- anions and two N atoms of one O-ethyl 3-methylpyridine-2-carboximidic acid molecule in a slightly distorted square-planar geometry, with Cu-N distances of 2.0483 (17) and 1.9404 (18) A, and Cu-Cl distances of 2.2805 (10) and 2.2275 (14) A. In addition, each Cu(II) atom is connected by one Cl- anion and the Cu(II) atom from a neighbouring molecule, with Cu...Cl and Cu...Cu distances of 2.9098 (13) and 3.4022 (12) A, respectively, and, therefore, a centrosymmetric dimer is formed. Adjacent molecular dimers are connected by pi-pi stacking interactions between pyridine rings to form a zigzag molecular chain. The molecular chains are also enforced by N-H...Cl and C-H...Cl interactions.

Details

ISSN :
01082701
Volume :
62
Database :
OpenAIRE
Journal :
Acta Crystallographica Section C Crystal Structure Communications
Accession number :
edsair.doi.dedup.....8517c04d7631cf56f37f285772701456