Back to Search
Start Over
Dichloro(O-ethyl 3-methylpyridine-2-carboximidic acid-κ2N,N′)copper(II)
- Source :
- Acta Crystallographica Section C Crystal Structure Communications. 62:m587-m589
- Publication Year :
- 2006
- Publisher :
- International Union of Crystallography (IUCr), 2006.
-
Abstract
- In the title compound, [CuCl2(C9H12N2O)], the Cu(II) atom is coordinated by two Cl- anions and two N atoms of one O-ethyl 3-methylpyridine-2-carboximidic acid molecule in a slightly distorted square-planar geometry, with Cu-N distances of 2.0483 (17) and 1.9404 (18) A, and Cu-Cl distances of 2.2805 (10) and 2.2275 (14) A. In addition, each Cu(II) atom is connected by one Cl- anion and the Cu(II) atom from a neighbouring molecule, with Cu...Cl and Cu...Cu distances of 2.9098 (13) and 3.4022 (12) A, respectively, and, therefore, a centrosymmetric dimer is formed. Adjacent molecular dimers are connected by pi-pi stacking interactions between pyridine rings to form a zigzag molecular chain. The molecular chains are also enforced by N-H...Cl and C-H...Cl interactions.
- Subjects :
- Molecular Structure
Nitrogen
Pyridines
Stereochemistry
Chemistry
Dimer
Stacking
3-Methylpyridine
Hydrogen Bonding
General Medicine
Crystal structure
Crystallography, X-Ray
General Biochemistry, Genetics and Molecular Biology
Ion
Crystallography
chemistry.chemical_compound
Pyridine
Organometallic Compounds
Molecule
Chlorine
Dimerization
Copper
Group 2 organometallic chemistry
Subjects
Details
- ISSN :
- 01082701
- Volume :
- 62
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section C Crystal Structure Communications
- Accession number :
- edsair.doi.dedup.....8517c04d7631cf56f37f285772701456