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High-capacity hydrogen storage in lithium and sodium amidoboranes

Authors :
William I. F. David
Ping Chen
Chaw-Keong Yong
Peter P. Edwards
Tom Autrey
Guotao Wu
Simon R. Johnson
Wendy J. Shaw
Abhi Karkamkar
Zhitao Xiong
Martin O. Jones
Publication Year :
2016

Abstract

The safe and efficient storage of hydrogen is widely recognized as one of the key technological challenges in the transition towards a hydrogen-based energy economy. Whereas hydrogen for transportation applications is currently stored using cryogenics or high pressure, there is substantial research and development activity in the use of novel condensed-phase hydride materials. However, the multiple-target criteria accepted as necessary for the successful implementation of such stores have not yet been met by any single material. Ammonia borane, NH3BH3, is one of a number of condensed-phase compounds that have received significant attention because of its reported release of approximately 12 wt% hydrogen at moderate temperatures (approximately 150 degrees C). However, the hydrogen purity suffers from the release of trace quantities of borazine. Here, we report that the related alkali-metal amidoboranes, LiNH2BH3 and NaNH2BH3, release approximately 10.9 wt% and approximately 7.5 wt% hydrogen, respectively, at significantly lower temperatures (approximately 90 degrees C) with no borazine emission. The low-temperature release of a large amount of hydrogen is significant and provides the potential to fulfil many of the principal criteria required for an on-board hydrogen store.

Details

Language :
English
Database :
OpenAIRE
Accession number :
edsair.doi.dedup.....83a0a5ce530d366d2972083f9c89c437