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The ν(CO) Vibrational Spectra of Planar Transition Metal Carbonyl Clusters
- Publication Year :
- 2003
-
Abstract
- The nu(CO) vibrational spectra of planar transition cluster carbonyls containing M(CO)(4) groups are studied. It is possible to anticipate qualitatively, both for the infrared and Raman, the band intensity changes associated with increasing metallic nature of the cluster. These enable a unification of the band patterns shown by the species reported. As for (idealized) spherical clusters, the spherical harmonic model (SHM), suitably modified, becomes of more general applicability as cluster size increases, although for smaller species the tensor harmonic model (THM) makes a contribution.
- Subjects :
- Chemistry
Infrared
Spherical harmonics
Metal carbonyl
Photochemistry
Molecular physics
Inorganic Chemistry
Metal
symbols.namesake
metal carbonyl
planar cluster
vibrational spectra
Transition metal
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visual_art.visual_art_medium
symbols
Cluster (physics)
Tensor
Physical and Theoretical Chemistry
Raman spectroscopy
Subjects
Details
- Language :
- English
- Database :
- OpenAIRE
- Accession number :
- edsair.doi.dedup.....82cb6bb619e6087da770a4c46d72184b