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Stereoselective Electro‐2‐deoxyglycosylation from Glycals
- Source :
- Angewandte Chemie. 132:15316-15320
- Publication Year :
- 2020
- Publisher :
- Wiley, 2020.
-
Abstract
- We report a novel and highly stereoselective electro-2-deoxyglycosylation from glycals. This method features excellent stereoselectivity, scope, and functional-group tolerance. This process can also be applied to the modification of a wide range of natural products and drugs. Furthermore, a scalable synthesis of glycosylated podophyllotoxin and a one-pot trisaccharide synthesis through iterative electroglycosylations were achieved.
Details
- ISSN :
- 15213757 and 00448249
- Volume :
- 132
- Database :
- OpenAIRE
- Journal :
- Angewandte Chemie
- Accession number :
- edsair.doi.dedup.....82a0356de8da77e74d84ee67c0b51daa