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Rotational Spectrum of Dichloromethane–Ne: Internal Dynamics and Cl Quadrupolar Hyperfine Effects
- Source :
- The journal of physical chemistry. A 119 (2015): 11813–11819. doi:10.1021/acs.jpca.5b09090, info:cnr-pdr/source/autori:Favero, Laura B.; Maris, Assimo; Paltrinieri, Laura; Caminati, Walther/titolo:Rotational Spectrum of Dichloromethane-Ne: Internal Dynamics and CI Quadrupolar Hyperfine Effects/doi:10.1021%2Facs.jpca.5b09090/rivista:The journal of physical chemistry. A/anno:2015/pagina_da:11813/pagina_a:11819/intervallo_pagine:11813–11819/volume:119
- Publication Year :
- 2015
- Publisher :
- American Chemical Society (ACS), 2015.
-
Abstract
- none 4 no The rotational spectra of three isotopologues, CH235Cl2···20Ne, CH235Cl37Cl···20Ne, and CH235Cl2···22Ne, of the complex dichloromethane-neon have been assigned and measured by molecular beam Fourier transform microwave spectroscopy. The corresponding tunnelling splittings-due to the motion of Ne from above to below the ClCCl plane-have been determined as E0+0- = 6.8900(5), 6.6630(4), and 6.3724(7) MHz, respectively. From these data the barrier to planarity has been obtained, B2 = 68.7 cm-1. In addition, the structure and the 35Cl (or 37Cl) quadrupole coupling constants have been determined. Favero, Laura B.; Maris, Assimo; Paltrinieri, Laura; Caminati, Walther Favero, Laura B.; Maris, Assimo; Paltrinieri, Laura; Caminati, Walther
- Subjects :
- Physical and Theoretical Chemistry: dichloromethane - neon molecular complex, molecular beam Fourier transform microwave spectroscopy, tunnelling splittings, large amplitude motions, chlorine quadrupole coupling constants
large amplitude motions
tunnelling splittings
chlorine quadrupole coupling constants
tunneling splitting
Chemistry
Physical and Theoretical Chemistry: dichloromethane - neon molecular complex
Analytical chemistry
Furier trasform high resolution microwave spectroscopy
Planarity testing
Spectral line
symbols.namesake
Fourier transform
rare gas adduct
Quadrupole
symbols
Isotopologue
molecular beam Fourier transform microwave spectroscopy
Rotational spectroscopy
Physical and Theoretical Chemistry
Hyperfine structure
Molecular beam
Subjects
Details
- ISSN :
- 15205215 and 10895639
- Volume :
- 119
- Database :
- OpenAIRE
- Journal :
- The Journal of Physical Chemistry A
- Accession number :
- edsair.doi.dedup.....815e7b0994739cfce29115efdf3cb300