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A methodology to construct a reduced chemical scheme for 2D-3D photochemical models: Application to Saturn

Authors :
Thibault Cavalié
Michel Dobrijevic
F. Billebaud
2 rue de l'Observatoire
CNRS
Centre National de la Recherche Scientifique (CNRS)
Laboratoire d'Astrophysique de Bordeaux [Pessac] (LAB)
Université de Bordeaux (UB)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)
Observatoire aquitain des sciences de l'univers (OASU)
Université Sciences et Technologies - Bordeaux 1-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)
Université Sciences et Technologies - Bordeaux 1
Laboratoire d'astrodynamique, d'astrophysique et d'aéronomie de bordeaux (L3AB)
Source :
Icarus, Icarus, Elsevier, 2011, ⟨10.1016/j.icarus.2011.04.027⟩, Icarus, Elsevier, 2011, 214 (1), pp.275-285. ⟨10.1016/j.icarus.2011.04.027⟩
Publication Year :
2011
Publisher :
HAL CCSD, 2011.

Abstract

We present a methodology to build a reduced chemical scheme adapted to the study of hydrocarbons in the atmospheres of giant planets and Titan. As an example, we have built a reduced chemical scheme, containing only 25 compounds and 46 reactions (including photolysis), which is well adapted to compute the abundance of the main hydrocarbons observed so far in the atmosphere of Saturn (CH 3 , CH 4 , C 2 H 2 , C 2 H 4 , C 2 H 6 , CH 3 C 2 H, C 3 H 8 and C 4 H 2 ). This scheme gives similar results, within the error bars of the model, as a 1D photochemical model using an initial chemical scheme containing 90 compounds and more than 600 reactions. As a consequence, such a methodology can be used to build a reduced scheme well adapted to future 2D (or 3D) photochemical models and GCMs.

Details

Language :
English
ISSN :
00191035 and 10902643
Database :
OpenAIRE
Journal :
Icarus, Icarus, Elsevier, 2011, ⟨10.1016/j.icarus.2011.04.027⟩, Icarus, Elsevier, 2011, 214 (1), pp.275-285. ⟨10.1016/j.icarus.2011.04.027⟩
Accession number :
edsair.doi.dedup.....7f6426cc9c8410ca831fdd43f1db513e