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A consistent set of formation properties of nucleic acid compounds

Authors :
C.B. Ould-Moulaye
C.G. Dussap
J.B. Gros
Source :
Thermochimica Acta. 375:93-107
Publication Year :
2001
Publisher :
Elsevier BV, 2001.

Abstract

Starting from formation properties of purines and pyrimidines, enthalpy of formation, Gibbs energy of formation, entropy of formation and heat capacity of several nucleosides, nucleotides and nucleotide-phosphates were calculated in dilute aqueous solution. For these calculations, the formation properties of ribose-1-phosphate were required and were calculated from data of various sources. Data for some enzymatic equilibrium constants were also used. To complete the set of formation properties of nucleosides and nucleotides, the energy contributions of some chemical bonds were calculated. The proposed values were reconciled with chemical and physical equilibrium data, validating the method of calculation used.

Details

ISSN :
00406031
Volume :
375
Database :
OpenAIRE
Journal :
Thermochimica Acta
Accession number :
edsair.doi.dedup.....7eee98adf211b542d82ed532333cda61
Full Text :
https://doi.org/10.1016/s0040-6031(01)00522-6