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A consistent set of formation properties of nucleic acid compounds
- Source :
- Thermochimica Acta. 375:93-107
- Publication Year :
- 2001
- Publisher :
- Elsevier BV, 2001.
-
Abstract
- Starting from formation properties of purines and pyrimidines, enthalpy of formation, Gibbs energy of formation, entropy of formation and heat capacity of several nucleosides, nucleotides and nucleotide-phosphates were calculated in dilute aqueous solution. For these calculations, the formation properties of ribose-1-phosphate were required and were calculated from data of various sources. Data for some enzymatic equilibrium constants were also used. To complete the set of formation properties of nucleosides and nucleotides, the energy contributions of some chemical bonds were calculated. The proposed values were reconciled with chemical and physical equilibrium data, validating the method of calculation used.
- Subjects :
- chemistry.chemical_classification
Quantitative Biology::Biomolecules
Physics::Biological Physics
Aqueous solution
Chemistry
education
Enthalpy
Condensed Matter Physics
Combustion
Quantitative Biology::Genomics
Heat capacity
Standard enthalpy of formation
Gibbs free energy
symbols.namesake
Chemical bond
Computational chemistry
Nucleic acid
symbols
Physical chemistry
Nucleotide
Physics::Chemical Physics
Physical and Theoretical Chemistry
Solubility
Instrumentation
Equilibrium constant
Subjects
Details
- ISSN :
- 00406031
- Volume :
- 375
- Database :
- OpenAIRE
- Journal :
- Thermochimica Acta
- Accession number :
- edsair.doi.dedup.....7eee98adf211b542d82ed532333cda61
- Full Text :
- https://doi.org/10.1016/s0040-6031(01)00522-6