Immobilization of a trimeric ruthenium cluster in mesoporous chromium terephthalate and its catalytic application

Authors :: Sanil E. Sivan
Kyung-Ryul Oh
Ji-Woong Yoon
Changho Yoo
Young Kyu Hwang
Source :: Dalton Transactions. 51:13189-13194
Publication Year :: 2022
Publisher :: Royal Society of Chemistry (RSC), 2022.
Abstract: Ru3 clusters were immobilized within the mesoporous cages of MIL-101(Cr) using diamine as anchoring units. The catalytic activity of isolated Ru3 clusters in the MOF pores was significantly improved compared to the bulk counterpart.

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