Organoruthenium derivative of the cyclic [H7P8W48O184]33? anion: [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27?

Authors :: Sib Sankar Mal
Ulrich Kortz
Michael H. Dickman
Nadeen H. Nsouli
Source :: Dalton Transactions. :2627
Publication Year :: 2007
Publisher :: Royal Society of Chemistry (RSC), 2007.
Abstract: Reaction of [Ru(p-cymene)Cl2]2 with [H7P8W48O184]33- (P8W48) in aqueous acidic medium results in the organometallic derivative [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27- (1); in addition to the four {Ru(p-cymene)(H2O)} units, an unusual WO6 group with four equatorial, terminal ligands is also grafted to the crown-shaped P8W48 precursor.

Subjects :: Aqueous solution
p-Cymene
Stereochemistry
Molecular Conformation
Medicinal chemistry
Ruthenium
Tungsten
Molecular conformation
Ion
Inorganic Chemistry
chemistry.chemical_compound
chemistry
Organometallic Compounds
Derivative (chemistry)

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