Back to Search
Start Over
Hydrophilization by coating of silylated polyoxazoline using sol-gel process
- Source :
- Progress in Organic Coatings, Progress in Organic Coatings, Elsevier, 2013, 76, pp.519-524. ⟨10.1016/j.porgcoat.2012.09.012⟩
- Publication Year :
- 2013
- Publisher :
- HAL CCSD, 2013.
-
Abstract
- International audience; Hybrid films prepared from TEOS and polyoxazolines (Si-POx-Si) crosslinking agents were coated on different substrates in order to modify their surface properties. The film cohesion and adhesion on sub- strates were expected through the hydrogen bonding of the polyoxazoline crosslinked network. Low molecular-weight ﰁ,ﰂ-unsaturated polyoxazolines (DA-PMOx)s were synthesized by a one step cationic ring-opening polymerization (CROP) of 2-methyl-2-oxazoline (MOx) with a good control over the molec- ular weight. Based on double thiol-ene coupling (d-TEC) a post-functionalization of DA-PMOx end chains gave in good yield polyoxazoline cross linker (Si-POx-Si). Glass and various polymer substrates (PP, PEI, POM, etc.) were spin coated by the organic-inorganic hybrid films through sol-gel process. AFM, SEM, visible reflectance spectroscopy and contact angle experiments allowed the full characterization of targeted surfaces and demonstrated the efficiency of the polyoxazoline coating.
- Subjects :
- Materials science
General Chemical Engineering
One-Step
02 engineering and technology
engineering.material
Solid surface energy
010402 general chemistry
01 natural sciences
Hydrophilization
Contact angle
Hybrid coating
Coating
Polymer chemistry
Materials Chemistry
Sol-gel
chemistry.chemical_classification
Organic Chemistry
Cationic polymerization
Polymer
021001 nanoscience & nanotechnology
0104 chemical sciences
Surfaces, Coatings and Films
[CHIM.POLY]Chemical Sciences/Polymers
Polymerization
chemistry
engineering
Polyoxazoline polymer
0210 nano-technology
Subjects
Details
- Language :
- English
- ISSN :
- 03009440
- Database :
- OpenAIRE
- Journal :
- Progress in Organic Coatings, Progress in Organic Coatings, Elsevier, 2013, 76, pp.519-524. ⟨10.1016/j.porgcoat.2012.09.012⟩
- Accession number :
- edsair.doi.dedup.....7bf406f6567adf8b7e54ac62b09ab75d