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Synthesis and Crystal Structures of the First Antimony(III) Aziridinides
- Source :
- Inorganic chemistry. 56(8)
- Publication Year :
- 2017
-
Abstract
- The first antimony(III) aziridinyl derivatives are reported. Treatment of anhydrous SbCl3 with N-lithioaziridine Li(Azn) (Azn = NC2H4) afforded the structurally unique heterobimetallic lithium/antimony(III) amide complex [Li3Sb(μ3-Cl)2(μ-Azn)4(THF)2]∞ (1). Homoleptic Sb2(Azn)6 (2) has become available for the first time through an amide group exchange reaction between Sb(NMe2)3 and 3 equiv of aziridine. The low-melting Sb2(Azn)6 exhibits a “weak dimer” structure in the crystal.
- Subjects :
- Stereochemistry
Dimer
chemistry.chemical_element
02 engineering and technology
Crystal structure
Aziridine
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
0104 chemical sciences
Inorganic Chemistry
chemistry.chemical_compound
Crystallography
chemistry
Antimony
Amide
Anhydrous
Lithium
Physical and Theoretical Chemistry
Homoleptic
0210 nano-technology
Subjects
Details
- ISSN :
- 1520510X
- Volume :
- 56
- Issue :
- 8
- Database :
- OpenAIRE
- Journal :
- Inorganic chemistry
- Accession number :
- edsair.doi.dedup.....7ab9af5185e980bc386ab3d2d840160a