Biocomposite based on zirconium and amine-grafted walnut shell with antibacterial properties for the removal of Alizarin red in water: batch and column studies

Recent progress has been made in the application of novel zirconium-loaded amine-grafted walnut shells as multifunctional adsorbents for the remediation of Alizarin red (AR) and bacteria in aqueous solutions. The morphology and functional groups of ACWNS@Zr were studied using Brunauer-Emmett-Teller (BET) techniques, X-ray diffraction (XRD), pH point of zero charges (pHpzc), scanning electron microscopy (SEM), and Fourier transform infrared (FTIR) spectroscopy. Adsorption and regeneration tests were carried out in batch and column mode. The ACWNS@Zr had a Langmuir maximum capacity of 415.5 ± 6.1 mg g