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Properties of casting solutions and ultrafiltration membranes based on fullerene-polyamide nanocomposites

Properties of casting solutions and ultrafiltration membranes based on fullerene-polyamide nanocomposites

Authors :
Galina Polotskaya
T. A. Kostereva
N. N. Sudareva
A. E. Polotskii
Anastasia V. Penkova
Source :
eXPRESS Polymer Letters, Vol 6, Iss 3, Pp 178-188 (2012)
Publication Year :
2012
Publisher :
Department of Polymer Engineering, Scientific Society of Mechanical Engineering, 2012.

Abstract

Poly(phenylene isophtalamide) (PA) was modified by fullerene C60 using solid-phase method. Novel ultrafiltra- tion membranes based on nanocomposites containing up to 10 wt% of fullerene and carbon black were prepared. Properties of PA/C60 composites in solutions were studied by light scattering and rheological methods. The relationship between char- acteristics of casting solutions and properties of nanocomposite membranes was studied. Scanning electron microscopy was used for structural characterization of the membranes. It was found that increase in fullerene content in nanocomposite enhances the membrane rigidity. All nanocomposite membranes were tested in dynamic (ultrafiltration) and static sorption experiments using a solution of protein mixture, with the purpose of studying protein sorption. The membranes modified by fullerene demonstrate the best values of flux reduced recovery after contact with protein solution. It was found that addition of fullerene C60 to the polymer improves technological parameters of the obtained composite membranes.

Details

ISSN :
1788618X
Volume :
6
Database :
OpenAIRE
Journal :
Express Polymer Letters
Accession number :
edsair.doi.dedup.....79996045bf8be5bfe8ed9fb09f2ec358
Full Text :
https://doi.org/10.3144/expresspolymlett.2012.20