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Dual mode temperature sensing through luminescence lifetimes of F- and O-coordinated Cr3+ sites in fluorosilicate glass-ceramics

Authors :
Xianping Fan
Abhishek Wadhwa
Xvsheng Qiao
Xianghua Zhang
Shuo Cui
Changjian Wang
Ronghua Ma
Zhejiang University
Institut des Sciences Chimiques de Rennes (ISCR)
Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes)
Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
LY16E020003, Natural Science Foundation of Zhejiang Province
2014DFB50100
51672243, NSFC, National Natural Science Foundation of China
2016QNA4005
2016FZA4007
Université de Rennes 1 (UR1)
Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées - Rennes (INSA Rennes)
Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Source :
RSC Advances, RSC Advances, 2017, 7 (83), pp.52435-52441. ⟨10.1039/c7ra10864h⟩, RSC Advances, Royal Society of Chemistry, 2017, 7 (83), pp.52435-52441. ⟨10.1039/c7ra10864h⟩
Publication Year :
2017
Publisher :
HAL CCSD, 2017.

Abstract

Luminescence lifetime based temperature sensing has an intrinsic immunity to the influence of external conditions, and dual mode thermometry is highly accurate due to its “self-calibration” merit. To develop thermometry with both features, we investigated the phase and microstructural evolution of Cr3+-doped calcium-fluorosilicate glass and glass-ceramics, which revealed different luminescent behavior relating to the different Cr3+ sites in the materials. From the photoluminescence (PL) spectra, the emission at 717 nm was derived from the O-coordinated octahedral sites, while the 1 μm super-broad emission was assigned to the F-coordinated octahedral sites. After an annealing treatment, cubic CaF2 nanocrystals were homogeneously precipitated in the glass-ceramics; thus, both the O-coordination in the residual glass phase and F-coordination in the CaF2 crystalline phase were strengthened. This led to the enhancement of both the emissions at 717 nm and 1 μm. The O-coordinated sites were relatively strong-field sites in which the fluorescence of Cr3+ originated from the radiative transitions of the two thermally coupled energy levels, 2E and 4T2, while the F-coordinated sites were relatively weak-field sites. Hence, the Cr3+ exhibits only one excited state 4T2, which is inactivated by radiative transitions and non-radiative transitions from the thermal quench. Based on the obtained results, the maximum relative temperature sensitivity coefficients are 0.76% K−1 at 498 K for the 717 nm emission and 0.47% K−1 at 351 K for the 1 μm emission. This provides the possibility of developing a dual mode temperature sensor with high precision only using a single material.

Details

Language :
English
ISSN :
20462069
Database :
OpenAIRE
Journal :
RSC Advances, RSC Advances, 2017, 7 (83), pp.52435-52441. ⟨10.1039/c7ra10864h⟩, RSC Advances, Royal Society of Chemistry, 2017, 7 (83), pp.52435-52441. ⟨10.1039/c7ra10864h⟩
Accession number :
edsair.doi.dedup.....7895a54d6b61dbced4f3b7613cbedb07