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Dual mode temperature sensing through luminescence lifetimes of F- and O-coordinated Cr3+ sites in fluorosilicate glass-ceramics
- Source :
- RSC Advances, RSC Advances, 2017, 7 (83), pp.52435-52441. ⟨10.1039/c7ra10864h⟩, RSC Advances, Royal Society of Chemistry, 2017, 7 (83), pp.52435-52441. ⟨10.1039/c7ra10864h⟩
- Publication Year :
- 2017
- Publisher :
- HAL CCSD, 2017.
-
Abstract
- Luminescence lifetime based temperature sensing has an intrinsic immunity to the influence of external conditions, and dual mode thermometry is highly accurate due to its “self-calibration” merit. To develop thermometry with both features, we investigated the phase and microstructural evolution of Cr3+-doped calcium-fluorosilicate glass and glass-ceramics, which revealed different luminescent behavior relating to the different Cr3+ sites in the materials. From the photoluminescence (PL) spectra, the emission at 717 nm was derived from the O-coordinated octahedral sites, while the 1 μm super-broad emission was assigned to the F-coordinated octahedral sites. After an annealing treatment, cubic CaF2 nanocrystals were homogeneously precipitated in the glass-ceramics; thus, both the O-coordination in the residual glass phase and F-coordination in the CaF2 crystalline phase were strengthened. This led to the enhancement of both the emissions at 717 nm and 1 μm. The O-coordinated sites were relatively strong-field sites in which the fluorescence of Cr3+ originated from the radiative transitions of the two thermally coupled energy levels, 2E and 4T2, while the F-coordinated sites were relatively weak-field sites. Hence, the Cr3+ exhibits only one excited state 4T2, which is inactivated by radiative transitions and non-radiative transitions from the thermal quench. Based on the obtained results, the maximum relative temperature sensitivity coefficients are 0.76% K−1 at 498 K for the 717 nm emission and 0.47% K−1 at 351 K for the 1 μm emission. This provides the possibility of developing a dual mode temperature sensor with high precision only using a single material.
- Subjects :
- Photoluminescence spectrum
Photoluminescence
Materials science
Luminescence
Annealing (metallurgy)
Radiative transitions
Thermometers
General Chemical Engineering
Calcium compounds
Glass ceramics
Analytical chemistry
02 engineering and technology
010402 general chemistry
Fluorosilicate glass
Annealing treatments
01 natural sciences
Spectral line
Luminescence lifetime
Calcium fluorosilicate
Radiative transfer
Ceramic materials
Temperature sensors
ComputingMilieux_MISCELLANEOUS
Excited states
Relative temperatures
General Chemistry
[CHIM.MATE]Chemical Sciences/Material chemistry
021001 nanoscience & nanotechnology
0104 chemical sciences
Nanocrystal
Excited state
Non-radiative transitions
0210 nano-technology
Subjects
Details
- Language :
- English
- ISSN :
- 20462069
- Database :
- OpenAIRE
- Journal :
- RSC Advances, RSC Advances, 2017, 7 (83), pp.52435-52441. ⟨10.1039/c7ra10864h⟩, RSC Advances, Royal Society of Chemistry, 2017, 7 (83), pp.52435-52441. ⟨10.1039/c7ra10864h⟩
- Accession number :
- edsair.doi.dedup.....7895a54d6b61dbced4f3b7613cbedb07