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Variation of triplet state properties of N-mTEG[60]fulleropyrrolidine bis-adducts as a function of the bond path between the addends

Authors :
Edward J. Land
René V. Bensasson
Konstantinos Kordatos
Sydney Leach
Maurizio Prato
Tatiana Da Ros
DA ROS, Tatiana
K., Kordato
Prato, Maurizio
E. J., Land
S., Leach
R. V., Bensasson
Source :
Research on Chemical Intermediates. 28:871-877
Publication Year :
2002
Publisher :
Springer Science and Business Media LLC, 2002.

Abstract

For a group of seven isomeric N-mTEG[60]fulleropyrrolidine bis-adducts (mTEG = CH2CH2OCH2CH2OCH2CH2OCH3), the quantum yields of singlet oxygen (O2, 1Δg) production and the maximum triplet molar absorption coefficients were found to be separately correlated with the shortest distances and with the number of bonds connecting the two addends on the fullerene sphere.

Details

ISSN :
15685675 and 09226168
Volume :
28
Database :
OpenAIRE
Journal :
Research on Chemical Intermediates
Accession number :
edsair.doi.dedup.....7890cacaa969e3c4bf0ff9e775f84c60
Full Text :
https://doi.org/10.1163/15685670260469483