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Theory of sampling (TOS) versus measurement uncertainty (MU) – A call for integration

Authors :
Claas Wagner
Kim H. Esbensen
Source :
Esbensen, K H & Wagner, C 2014, ' Theory of sampling (TOS) versus measurement uncertainty (MU) : A call for integration ', Trends in Analytical Chemistry, vol. 57, pp. 93-106 . https://doi.org/10.1016/j.trac.2014.02.007
Publication Year :
2014
Publisher :
Elsevier BV, 2014.

Abstract

We assess current approaches to measurement uncertainty (MU) with respect to the complete ensemble of sources affecting the measurement process, in particular the extent to which sampling errors as set out in the Theory of Sampling (TOS) are appropriately considered in the GUM and EURACHEM/CITAC guides. All pre-analysis sampling steps play an important, often dominant role in the total uncertainty budget, thereby critically affecting the validity of MU estimates, but most of these contributions are not included in the current MU framework. The TOS constitutes the only complete theoretical platform for dealing appropriately with the entire pathway from field sample to test portion. We here propose a way to reconcile the often strongly felt differences between MU and TOS. There is no need to debate terminology, as both TOS and MU can be left with their current usages.

Details

ISSN :
01659936
Volume :
57
Database :
OpenAIRE
Journal :
TrAC Trends in Analytical Chemistry
Accession number :
edsair.doi.dedup.....7769856bd1e7049efb90209a135673d7
Full Text :
https://doi.org/10.1016/j.trac.2014.02.007