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Counterions of BINAP-Pt(II) and -Pd(II) complexes: novel catalysts for highly enantioselective Diels-Alder reaction
- Source :
- Organic letters. 1(13)
- Publication Year :
- 2000
-
Abstract
- [formula: see text] Platinum and palladium chiral bisphosphine complexes and their counterion effects in asymmetric Diels-Alder reactions have been investigated. The reaction of cyclopentadiene and various bidentate dienophiles in the presence of a catalytic amount of Pt(II)- or Pd(II)-BINAP complex proceeds with excellent endo/exo selectivity as well as endo enantioselectivity (up to 99% ee).
- Subjects :
- chemistry.chemical_classification
Cyclopentadiene
Stereochemistry
Organic Chemistry
Enantioselective synthesis
chemistry.chemical_element
Stereoisomerism
Cyclopentanes
Naphthalenes
Biochemistry
Medicinal chemistry
Catalysis
chemistry.chemical_compound
chemistry
Physical and Theoretical Chemistry
Counterion
Platinum
Palladium
BINAP
Diels–Alder reaction
Subjects
Details
- ISSN :
- 15237060
- Volume :
- 1
- Issue :
- 13
- Database :
- OpenAIRE
- Journal :
- Organic letters
- Accession number :
- edsair.doi.dedup.....753e8157033b6c6d49f5bf959b51759d