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Stereo selective synthesis of C3–C12 fragment of iriomoteolide-1a
- Source :
- Journal of Saudi Chemical Society, Vol 22, Iss 2, Pp 165-172 (2018)
- Publication Year :
- 2016
- Publisher :
- Elsevier BV, 2016.
-
Abstract
- A convergent and flexible synthetic route for the synthesis of C3–C12 fragment of iriomoteolide-1a is described. The key steps are: Mannich reaction, Keck asymmetric allylation, Sharpless asymmetric epoxidation and cross-metathesis protocol.
- Subjects :
- Sharpless epoxidation
Keck allylation
Cross-metathesis
Chemistry(all)
010405 organic chemistry
Stereochemistry
Fragment (computer graphics)
Chemistry
Iriomoteolide-1a
General Chemistry
010402 general chemistry
01 natural sciences
0104 chemical sciences
lcsh:Chemistry
lcsh:QD1-999
Mannich reaction
Subjects
Details
- ISSN :
- 13196103
- Database :
- OpenAIRE
- Journal :
- Journal of Saudi Chemical Society
- Accession number :
- edsair.doi.dedup.....747e4ff774646c6ec2e864c2ba10ee05
- Full Text :
- https://doi.org/10.1016/j.jscs.2016.01.008