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Copper-catalyzed trifluoromethylthiolation of aryl halides with diverse directing groups
- Source :
- Organic letters. 16(15)
- Publication Year :
- 2014
-
Abstract
- The expansion of cross-coupling components in Cu-catalyzed C–X bond forming reactions have received much attention recently. A novel Cu-catalyzed trifluoromethylthiolation of aryl bromides and iodides with the assistance of versatile directing groups such as pyridyl, methyl ester, amide, imine and oxime was reported. CuBr was used as the catalyst, and 1,10-phenanthroline as the ligand. By changing the solvent from acetonitrile to DMF, the coupling process could even take place at room temperature.
- Subjects :
- Hydrocarbons, Fluorinated
Molecular Structure
Ligand
Aryl
Organic Chemistry
Imine
Temperature
Oxime
Biochemistry
Catalysis
Hydrocarbons, Brominated
chemistry.chemical_compound
chemistry
Amide
Polymer chemistry
Organic chemistry
Molecule
Sulfhydryl Compounds
Physical and Theoretical Chemistry
Hydrocarbons, Iodinated
Acetonitrile
Copper
Subjects
Details
- ISSN :
- 15237052
- Volume :
- 16
- Issue :
- 15
- Database :
- OpenAIRE
- Journal :
- Organic letters
- Accession number :
- edsair.doi.dedup.....7415eef551ef67fa1d29e6ea3b58447d