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Using sodium acetate for the synthesis of [Au(NHC)X] complexes
- Source :
- DALTON TRANSACTIONS
- Publication Year :
- 2020
- Publisher :
- Royal Society of Chemistry (RSC), 2020.
-
Abstract
- The role of sodium acetate in the synthesis of [Au(NHC)Cl] complexes was examined. The use of this base was also investigated for the activation of C-H and S-H bonds by experimental and computational methods. The synthetic use of NaOAc to assemble these complexes is applicable to a wide range of NHCs and proceeds under air, under mild conditions and using technical grade green solvents.
Details
- ISSN :
- 14779234 and 14779226
- Volume :
- 49
- Database :
- OpenAIRE
- Journal :
- Dalton Transactions
- Accession number :
- edsair.doi.dedup.....73930adc8010b2c494b487185cd81d06