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The oxalic acid: 2-chloroacetamide crystallization: A new revelation

Authors :
Frédéric Capet
Pascal Roussel
R.R. Choudhury
R. Chitra
Laboratoire de Physique Théorique des Liquides (LPTL)
Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS)
Max Planck Institute for Extraterrestrial Physics (MPE)
Max-Planck-Gesellschaft
Unité de Catalyse et Chimie du Solide - UMR 8181 (UCCS)
Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)
Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille
Solid State Physics Division (BHARC)
Bhabha Atomic Research Centre (BARC)
Government of India, Department of Atomic Energy-Government of India, Department of Atomic Energy
Source :
SOLID STATE PHYSICS: PROCEEDINGS OF THE 57TH DAE SOLID STATE PHYSICS SYMPOSIUM 2012, SOLID STATE PHYSICS: PROCEEDINGS OF THE 57TH DAE SOLID STATE PHYSICS SYMPOSIUM 2012, 2012, Indian Institute of Technology, India. pp.860-861, 57TH DAE SOLID STATE PHYSICS SYMPOSIUM 2012, 57TH DAE SOLID STATE PHYSICS SYMPOSIUM 2012, 2012, Mumbai (India), France. pp.860-861, SOLID STATE PHYSICS: PROCEEDINGS OF THE 57TH DAE SOLID STATE PHYSICS SYMPOSIUM 2012, 2013, Indian Institute of Technology, India. pp.860-861
Publication Year :
2012
Publisher :
HAL CCSD, 2012.

Abstract

The OH of COOH can acts as both donor and acceptor of hydrogen bond. OH of COOH as an acceptor was primarily observed in Oxalic acid Amide complexes. In order to further understand the packing in these complexes, oxalic acid was complexed with 2-tricholoroacetamide. This crystallization resulted in the formation of ammonium tetraoxalate dehydrate. A result similar to what was observed in complexation of oxalic acid with amide containing amino acids (asparagine and glutamine). Interestingly in all these cases, the amide bond is broken, to form the ammonium ion when trying to complex with oxalic acid.

Subjects

Subjects :
chemistry.chemical_classification
Hydrogen bond
Oxalic acid
020206 networking & telecommunications
02 engineering and technology
[CHIM.INOR]Chemical Sciences/Inorganic chemistry
Amino acid
Glutamine
chemistry.chemical_compound
chemistry
Amide
Polymer chemistry
0202 electrical engineering, electronic engineering, information engineering
Peptide bond
Organic chemistry
020201 artificial intelligence & image processing
Asparagine
Chloroacetamide
ComputingMilieux_MISCELLANEOUS

Details

Language :
English
Database :
OpenAIRE
Journal :
SOLID STATE PHYSICS: PROCEEDINGS OF THE 57TH DAE SOLID STATE PHYSICS SYMPOSIUM 2012, SOLID STATE PHYSICS: PROCEEDINGS OF THE 57TH DAE SOLID STATE PHYSICS SYMPOSIUM 2012, 2012, Indian Institute of Technology, India. pp.860-861, 57TH DAE SOLID STATE PHYSICS SYMPOSIUM 2012, 57TH DAE SOLID STATE PHYSICS SYMPOSIUM 2012, 2012, Mumbai (India), France. pp.860-861, SOLID STATE PHYSICS: PROCEEDINGS OF THE 57TH DAE SOLID STATE PHYSICS SYMPOSIUM 2012, 2013, Indian Institute of Technology, India. pp.860-861
Accession number :
edsair.doi.dedup.....70ee5f7b9f5cb2c2bbac9bea7ccacb0d

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