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Benzylium versus Tropylium Ion Dichotomy: Vibrational Spectroscopy of Gaseous C8H9+ Ions

Authors :
Philippe Maître
Simonetta Fornarini
Barbara Chiavarino
Otto Dopfer
Maria Elisa Crestoni
Source :
Angewandte Chemie. 124:5031-5033
Publication Year :
2012
Publisher :
Wiley, 2012.

Abstract

Definitely different: the path towards sorting out a long-standing dichotomy in carbocation chemistry is disclosed by infrared multiple photon dissociation spectroscopy of tropylium and benzylium isomers of C(8)H(9)(+) ions.

Details

ISSN :
00448249
Volume :
124
Database :
OpenAIRE
Journal :
Angewandte Chemie
Accession number :
edsair.doi.dedup.....7081a81b11e14bf210afe8c99961095f
Full Text :
https://doi.org/10.1002/ange.201200558