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Shaping of ceria-based single solid oxide cells combining tape-casting, screen-printing and infiltration

Authors :
Thierry Chartier
Pierre-Marie Geffroy
L. Guesnet
J.-C. Grenier
Jean-Marc Bassat
Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB)
Université de Bordeaux (UB)-Institut Polytechnique de Bordeaux-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Institut de Recherche sur les CERamiques (IRCER)
Institut des Procédés Appliqués aux Matériaux (IPAM)
Université de Limoges (UNILIM)-Université de Limoges (UNILIM)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
This research was partly supported by a French regional fellowship 'Région Nouvelle Aquitaine' (for L.G.). LG, JCG and JMB are grateful for the financial support obtained through the ANR project ECOREVE (ANR-18-CE05-0036-01). All authors acknowledge the French group GDR HysPac for fruitful discussions. Finally, the authors are grateful to the Solvay company (France) for providing the chemical precursors and powders employed in this work.
ANR-18-CE05-0036,ECOREVE,EleCtrOdes architecturées pour la Réalisation d'Electrolyseurs de la Vapeur d'Eau à haute température(2018)
Source :
Journal of the European Ceramic Society, Journal of the European Ceramic Society, Elsevier, 2020, 40 (15), pp.5662-5669. ⟨10.1016/j.jeurceramsoc.2020.07.026⟩
Publication Year :
2020
Publisher :
Elsevier BV, 2020.

Abstract

International audience; This study describes the development of a shaping process involving GDC10 (Ce0.9Gd0.1O1.95) as an electrolyte for Solid Oxide Cells operating at low temperature (500−600 °C). The goal is to build a single cell of porous/dense/porous GDC10 layers while adapting the porous layer thicknesses, which are infiltrated by catalysts to prepare efficient GDC-base composites. Two shaping processes were used to make the cell. The first process is die pressing of the electrolyte powder followed by the infiltration of a screen-printed porous backbone. The second shaping process consists of preparing a porous/dense/porous (30 μm/≈ 400 μm/30 μm) cell in a single step by combining tape-casting and screen-printing processes followed by the infiltration of the previous catalyst.

Details

ISSN :
09552219
Volume :
40
Database :
OpenAIRE
Journal :
Journal of the European Ceramic Society
Accession number :
edsair.doi.dedup.....701b00c31f53555cced05b136c84fb9a
Full Text :
https://doi.org/10.1016/j.jeurceramsoc.2020.07.026