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Esterification of Carboxylic Acids with Aryl Halides via the Merger of Paired Electrolysis and Nickel Catalysis
- Source :
- The Journal of Organic Chemistry. 86:15906-15913
- Publication Year :
- 2021
- Publisher :
- American Chemical Society (ACS), 2021.
-
Abstract
- Electrochemistry has been successfully applied in metal catalysis to avoid the usage of chemical redox agents. This strategy proved to be a powerful approach to construct carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds. However, most of the developed methods are based on either anodic oxidation or cathodic reduction, in which a sacrificial reaction occurs at the counter electrode. Paired electrolysis merging with metal catalysis is underdeveloped, wherein both anodic and cathodic processes are taking place simultaneously. Herein, we demonstrated that by using esterification of carboxylic acids with aryl halides via paired electrolysis using nickel as the catalyst the respective aryl esters were obtained in good to excellent yields at room temperature in an undivided electrochemical cell.
- Subjects :
- Electrolysis
010405 organic chemistry
Chemistry
Aryl
Organic Chemistry
Halide
chemistry.chemical_element
010402 general chemistry
Electrochemistry
01 natural sciences
Redox
Combinatorial chemistry
0104 chemical sciences
Catalysis
Electrochemical cell
law.invention
chemistry.chemical_compound
Nickel
law
Subjects
Details
- ISSN :
- 15206904 and 00223263
- Volume :
- 86
- Database :
- OpenAIRE
- Journal :
- The Journal of Organic Chemistry
- Accession number :
- edsair.doi.dedup.....6f280457ec5660adf901261e82408c04